| Título | High alkylation activities of ball-milled synthesized low-load supported iron oxide nanoparticles on mesoporous aluminosilicates |
|---|---|
| Autores | Pineda, Antonio , Balu, Alina M. , Manuel Campelo, Juan , Luque, Rafael , Angel Romero, Antonio , SERRANO RUIZ, JUAN CARLOS |
| Publicación externa | Si |
| Medio | Catal. Today |
| Alcance | Article |
| Naturaleza | Científica |
| Cuartil JCR | 1 |
| Cuartil SJR | 1 |
| Impacto JCR | 2.98 |
| Impacto SJR | 1.469 |
| Fecha de publicacion | 30/06/2012 |
| ISI | 000305368600009 |
| DOI | 10.1016/j.cattod.2012.02.028 |
| Abstract | Low-load iron oxide nanoparticles on Al-SBA-15 prepared using a novel dry milling approach exhibited excelling activities in the microwave-assisted akylation of toluene with benzyl chloride (Lewis acids promoted reaction) and benzyl alcohol (Bronsted acids promoted reaction) as compared to the parent Al-SBA-15 and similar iron oxide nanoparticles supported on Al-MCM-41 materials. Materials prepared using the milling protocol possessed remarkably low iron loadings (<0.1 wt%) but featured highly accessible sites and small nanoparticle sizes that seemed to be related to the observed differences in activities in the systems. (C) 2012 Elsevier B.V. All rights reserved. |
| Palabras clave | Supported nanoparticles; Iron oxide nanoparticles; Ball milling; Mechanochemistry; Alkylations |
| Miembros de la Universidad Loyola |